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Facile fabrication of superhydrophobic coatings on concrete substrate

Pingping Hou (State Key Laboratory of High Performance Civil Engineering Materials, State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences, Shanghai, China)
Zhaohui Zhan (Jiangsu Sobute New Materials Co. Ltd, Nanjing, China)
Shuai Qi (Jiangsu Sobute New Materials Co. Ltd, Nanjing, China)
Yingjie Ma (Jiangsu Sobute New Materials Co. Ltd, Nanjing, China)
Bo Li (Jiangsu Sobute New Materials Co. Ltd, Nanjing, China)
Dewen Sun (Jiangsu Colourful Building Materials (Group) Co., Ltd., Nanjing, China)
Qianping Ran (School of Materials Science and Engineering, Southeast University, Nanjing, China)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 5 August 2021

Issue publication date: 13 May 2022

179

Abstract

Purpose

The purpose of this study is to prepare a chemically stable superhydrophobic coating with remarkable mechanical properties and concrete protective properties.

Design/methodology/approach

One synthetic step was adopted to prepare superhydrophobic coating. The process and product were analyzed and confirmed by fourier transform-infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), water contact angle (WCA), transmission electron microscopy (TEM), scanning electron microscope (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The mechanical properties were confirmed by tensile test. The concrete protective properties were confirmed by solution immersion test and rapid chloride migration coefficient test.

Findings

MSiO2 nanoparticles (NPs) were chosen to enhance the hydrophobicity of fluorosilicone coatings. With a 4:1 mass ratio of fluorosilicone resin and MSiO2 NPs, the coatings show superhydrophobicity with a WCA of 156° and a SA of 3.1°. In addition, the tensile mechanical property was improved, and the chloride ion diffusion coefficient was decreased significantly after the addition of MSiO2 NPs.

Practical implications

This new fluorosilicone coating hybrid by MSiO2 NPs could be applied as a concrete protective layer with properties of self-cleaning, antifouling, etc.

Originality/value

Introduction of MSiO2 NPs hybrid to prepare fluorosilicone coating with superhydrophobicity on concrete surface has not been systematically studied previously.

Keywords

Acknowledgements

This work was supported financially by the National Key R&D Program of China (No. 2017YFB0309904), the National Natural Science Foundation of China (No. 52008188) and National Natural Science Foundation of China-Joint Fund of Shandong Province (U1706222). The authors thank the International Science Editing (www.internationalscienceediting.com) for editing this manuscript.

Citation

Hou, P., Zhan, Z., Qi, S., Ma, Y., Li, B., Sun, D. and Ran, Q. (2022), "Facile fabrication of superhydrophobic coatings on concrete substrate", Pigment & Resin Technology, Vol. 51 No. 4, pp. 420-425. https://doi.org/10.1108/PRT-01-2021-0010

Publisher

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Emerald Publishing Limited

Copyright © 2021, Emerald Publishing Limited

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