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Study on self-cleaning performance and hydrophobicity of TiO2/silane coatings

A. Syafiq (UM Power Energy Dedicated Advanced Centre, Wisma R&D, Level 4, Jalan Pantai Murni, University of Malaya, Kuala Lumpur, Malaysia)
A.K. Pandey (Research Centre for Nano-Materials and Energy Technology (RCNMET), School of Science and Technology, Sunway University, No. 5, Jalan Universiti, Bandar Sunway, Petaling Jaya, Selangor Darul Ehsan, Malaysia)
Vengadaesvaran Balakrishnan (UM Power Energy Dedicated Advanced Centre, Wisma R&D, Level 4, Jalan Pantai Murni, University of Malaya, Kuala Lumpur, Malaysia)
Nasrudin Abd Rahim (UM Power Energy Dedicated Advanced Centre, Wisma R&D, Level 4, Jalan Pantai Murni, University of Malaya, Kuala Lumpur, Malaysia)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 31 December 2018

Issue publication date: 2 January 2024

453

Abstract

Purpose

The paper aims to investigate the effect of Degussa P-25 Titanium Dioxide (TiO2) nanoparticles on hydrophobicity and self-cleaning ability as a single organic coating on glass substrate.

Design/methodology/approach

Two methods have been used to enhance the hydrophobicity on glass substrates, namely, surface modification by using low surface energy isooctyltrimethoxysilane (ITMS) solution and construction of rough surface morphology using Degussa P-25 TiO2 nanoparticles with simple bottom-up approach. The prepared sol was applied onto glass substrate using dip-coating technique and stoved in the vacuum furnace 350°C.

Findings

The ITMS coating with nano TiO2 pigment has modified the glass substrate surface by achieving the water contact angle as high as 169° ± 2° and low sliding angle of 0° with simple and low-cost operation. The solid and air phase interface has created excellent anti-dirt and self-cleaning properties against dilute ketchup solution, mud and silicon powder.

Research limitations/implications

Findings will be useful in the development of self-cleaning and anti-dirt coating for photovoltaic panels.

Practical implications

Sol method provides the suitable medium for the combination of organic–inorganic network to achieve high superhydrophobicity and optimum self-cleaning ability.

Originality/value

Application of blended organic–inorganic sol as self-cleaning and anti-dirt coating film.

Keywords

Acknowledgements

The authors thank the technical and financial assistance of UM Power Energy Dedicated Advanced Centre (UMPEDAC) and the Higher Institution Centre of Excellence (HICoE) Program Research Grant, UMPEDAC – 2016 (MOHE HICOE – UMPEDAC).

Citation

Syafiq, A., Pandey, A.K., Balakrishnan, V. and Rahim, N.A. (2024), "Study on self-cleaning performance and hydrophobicity of TiO2/silane coatings", Pigment & Resin Technology, Vol. 53 No. 1, pp. 1-9. https://doi.org/10.1108/PRT-02-2018-0010

Publisher

:

Emerald Publishing Limited

Copyright © 2019, Emerald Publishing Limited

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