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A copper-(lignin/silica/fatty acids) complex as an antioxidant/electrical conductivity agent for rubber composites (Part iii)

Hoda Sabry Othman (Department of Green Chemistry, National Research Centre, Giza, Egypt)
Maher A. El-Hashash (Department of Chemistry, Faculty of Science, Ain Shams University, Cairo, Egypt)
S.H. El-Sabbagh (Department of Polymers and Pigments, National Research Centre, Giza, Egypt)
A.A. Ward (Microwave Physics and Dielectrics Department, National Research Centre, Giza, Egypt)
Galal A.M. Nawwar (Department of Green Chemistry, National Research Centre, Giza, Egypt)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 5 April 2021

Issue publication date: 3 January 2022

184

Abstract

Purpose

Calcium and Zinc lignates were proven to be good antioxidants for rubber composites. The purpose of this paper is to evaluate the copper lignate antioxidant activity along with evaluating its electrical conductivity in rubber composites.

Design/methodology/approach

The antioxidant activity of the Cu-LSF complex was compared with that of standard commercial antioxidant additives as a green alternative. The rheological characteristics, thermal aging and mechanical and electrical properties were evaluated for the NBR vulcanizates containing the different antioxidants in the presence or absence of coupling agents.

Findings

Results revealed that the Cu-LSF complex (5 phr) can function as a compatibilizing, antioxidant and electrical conductivity agent.

Originality/value

The new copper complex prepared from paper-pulping black liquor of wastes could be used as a green antioxidant and electrical conductivity agent in rubber composites.

Keywords

Acknowledgements

The authors are grateful to the National Research Centre (NRC) for their financial support.

Conflict of interest: There are no conflicts of interest to declare.

Citation

Othman, H.S., El-Hashash, M.A., El-Sabbagh, S.H., Ward, A.A. and Nawwar, G.A.M. (2022), "A copper-(lignin/silica/fatty acids) complex as an antioxidant/electrical conductivity agent for rubber composites (Part iii)", Pigment & Resin Technology, Vol. 51 No. 1, pp. 42-52. https://doi.org/10.1108/PRT-10-2020-0112

Publisher

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Emerald Publishing Limited

Copyright © 2021, Emerald Publishing Limited

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