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Journal cover: Anti-Corrosion Methods and Materials

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Online from: 1954

Subject Area: Mechanical & Materials Engineering

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N-3-hydroxyl-2-naphthoyl hydrazone derivatives as inhibitors for corrosion of carbon steel in H2SO4 acid solution


Document Information:
Title:N-3-hydroxyl-2-naphthoyl hydrazone derivatives as inhibitors for corrosion of carbon steel in H2SO4 acid solution
Author(s):A.S. Fouda, (Chemistry Department, Faculty of Science, Mansoura University, El-Mansoura, Egypt), S.A. EL-Sayyad, (Chemistry Department, Faculty of Science, Mansoura University, El-Mansoura, Egypt), M. Abdallah, (Chemistry Department, Faculty of Applied Science, Umm Al-Qura University, Makkah Al Mukaramha, Saudi Arabia)
Citation:A.S. Fouda, S.A. EL-Sayyad, M. Abdallah, (2011) "N-3-hydroxyl-2-naphthoyl hydrazone derivatives as inhibitors for corrosion of carbon steel in H2SO4 acid solution", Anti-Corrosion Methods and Materials, Vol. 58 Iss: 2, pp.63 - 69
Keywords:Corrosion inhibitors, Steels, Sulphuric acid
Article type:Research paper
DOI:10.1108/00035591111110705 (Permanent URL)
Publisher:Emerald Group Publishing Limited
Abstract:

Purpose – The purpose of this paper is to investigate the inhibiting properties of four N-3-hydroxyl-2-naphthoyl hydrazone derivatives in 0.5?M H2SO4 solution and to study the mechanism of their action.

Design/methodology/approach – The effect of various parameters on the behavior of these inhibitors has been studied using the weight loss and polarization measurements.

Findings – The inhibiting action of the investigated compounds depends primarily on their concentration and molecular size. The compounds act as mixed type inhibitors and function via adsorption on carbon steel surface, which follows Frumkin adsorption isotherm. The addition of KI, KBr and KSCN to N-3-hydroxyl-2-naphthoyl hydrazone derivatives had a synergistic effect in enhancing the efficiency of corrosion inhibition.

Originality/value – This paper provides useful information regarding inhibition effect of N-3-hydroxyl-2-naphthoyl hydrazone derivatives and clarifies the role of the molecular structure and substituents on the inhibition efficiency of these investigated compounds on the corrosion of carbon steel in acidic solutions.



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